Skip to main content


Safe Work Australia
HomeHCIS Home
FeedbackFeedback

Hazardous Chemical Information System (HCIS)




Hazardous Chemical Details

Cas Number 495-54-5
Chemical Name 1,3-Benzenediamine, 4-(phenylazo)-
Chemical Synonym
Hazard Category Acute toxicity – category 4
Germ cell mutagenicity – category 2
Eye damage – category 1
Skin irritation – category 2
Skin sensitisation – category 1
Carcinogenicity – category 2
Hazard Statement H302 (Harmful if swallowed)
H341 (Suspected of causing genetic defects)
H318 (Causes serious eye damage)
H315 (Causes skin irritation)
H317 (May cause an allergic skin reaction)
H351 (Suspected of causing cancer)
Pictogram Pictogram of Exclamation Mark GHS07 (Exclamation Mark)
Pictogram of Health Hazard GHS08 (Health Hazard)
Pictogram of Corrosion GHS05 (Corrosion)
Signal Word Danger
Cut-offs
Notes 8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.)
Sources N (The classification information for this entry was provided by the National Industrial Chemical Notification and Assessment Scheme)

Hazardous Chemical History

Date Description
19/07/2019 Hazard Category modified from
[HC062:Acute toxicity – category 4,
HC098:Germ cell mutagenicity – category 2,
HC085:Eye damage – category 1,
HC083:Skin irritation – category 2,
HC092:Skin sensitisation – category 1]

to
[HC062:Acute toxicity – category 4,
HC098:Germ cell mutagenicity – category 2,
HC085:Eye damage – category 1,
HC083:Skin irritation – category 2,
HC092:Skin sensitisation – category 1,
HC102:Carcinogenicity – category 2]

Pictogram modified from
[GHS07,GHS08,GHS05]
to
[GHS05,GHS07,GHS08]
Hazard Statement modified from
[H302 Harmful if swallowed;
H341 Suspected of causing genetic defects;
H318 Causes serious eye damage;
H315 Causes skin irritation;
H317 May cause an allergic skin reaction]
to
[H302 Harmful if swallowed;
H341 Suspected of causing genetic defects;
H318 Causes serious eye damage;
H315 Causes skin irritation;
H317 May cause an allergic skin reaction;
H351 Suspected of causing cancer]
25/06/2018 Hazard Category modified from
[HC062:Acute toxicity – category 4,
HC098:Germ cell mutagenicity – category 2,
HC102:Carcinogenicity – category 2,
HC085:Eye damage – category 1,
HC083:Skin irritation – category 2,
HC112:Specific target organ toxicity (repeated exposure) – category 2,
HC092:Skin sensitisation – category 1]

to
[HC062:Acute toxicity – category 4,
HC098:Germ cell mutagenicity – category 2,
HC085:Eye damage – category 1,
HC083:Skin irritation – category 2,
HC092:Skin sensitisation – category 1]

Hazard Statement modified from
[H302 Harmful if swallowed;
H341 Suspected of causing genetic defects;
H351 Suspected of causing cancer;
H318 Causes serious eye damage;
H315 Causes skin irritation;
H373 May cause damage to organs through prolonged or repeated exposure if swallowed;
H317 May cause an allergic skin reaction]
to
[H302 Harmful if swallowed;
H341 Suspected of causing genetic defects;
H318 Causes serious eye damage;
H315 Causes skin irritation;
H317 May cause an allergic skin reaction]
09/05/2018 Signal Word modified from
[]
to
[Danger]
Pictogram modified from
[]
to
[GHS07,GHS08,GHS05]
Hazard Statement modified from
[H302 Harmful if swallowed;
H341 Suspected of causing genetic defects;
H351 Suspected of causing cancer;
H318 Causes serious eye damage;
H315 Causes skin irritation;
H373 May cause damage to organs through prolonged or repeated exposure if swallowed;
H317 May cause an allergic skin reaction]
to
[H302 ;
H341 ;
H351 ;
H318 ;
H315 ;
H373 May cause damage to organs through prolonged or repeated exposure if swallowed;
H317 ]
Notes modified from
[]
to
[8]
Sources modified from
[]
to
[N]
20/01/2017 Chemical Deleted
20/01/2017 Chemical Added



Copyright
Disclaimer
Feedback
Privacy