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| Cas Number | 137-30-4 |
| Chemical Name | ziram (ISO) |
| Chemical Synonym |
zinc bis dimethyldithiocarbamate Zinc, bis(dimethylcarbamodithioato-S,S')-, (T-4)- |
| Hazard Category |
Hazardous to the aquatic environment (acute) – category 1 Hazardous to the aquatic environment (chronic) – category 1 Acute toxicity (inhalation) - category 2 Acute toxicity (ingestion) - category 4 Eye damage – category 1 Skin sensitisation – category 1 Specific target organ toxicity (single exposure) – category 3 Specific target organ toxicity (repeated exposure) – category 2 Skin irritation – category 2 |
| Hazard Statement |
H410 (Very toxic to aquatic life with long-lasting effects) H330 (Fatal if inhaled) H302 (Harmful if swallowed) H318 (Causes serious eye damage) H317 (May cause an allergic skin reaction) H335 (May cause respiratory irritation) H373 (May cause damage to organs through prolonged or repeated exposure) H315 (Causes skin irritation) |
| Pictogram |
GHS06 (Skull and Crossbones) 
GHS05 (Corrosion) 
GHS08 (Health Hazard) 
GHS09 (Environment) |
| Signal Word | Danger |
| Cut-offs | M = 100 (acute) |
| Notes |
8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.) |
| Sources |
N (The classification information for this entry was provided by the National Industrial Chemical Notification and Assessment Scheme) EU (Classification information for chemical is taken from the European Union’s Classification, Labelling and Packaging (CLP) Regulation.) |
Hazardous Chemical History
| Date | Description |
|---|---|
| 30/04/2021 |
CutOffs modified from [M = 100 (acute)] to [ M = 100 (acute) ]Hazard Category modified from [HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1, HC065:Acute toxicity (inhalation) - category 2, HC072:Acute toxicity (ingestion) - category 4, HC085:Eye damage – category 1, HC092:Skin sensitisation – category 1, HC110:Specific target organ toxicity (single exposure) – category 3, HC112:Specific target organ toxicity (repeated exposure) – category 2] to [HC065:Acute toxicity (inhalation) - category 2, HC072:Acute toxicity (ingestion) - category 4, HC083:Skin irritation – category 2, HC085:Eye damage – category 1, HC092:Skin sensitisation – category 1, HC110:Specific target organ toxicity (single exposure) – category 3, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1] Pictogram modified from [GHS06,GHS05,GHS08,GHS09] to [GHS05,GHS06,GHS08,GHS09] Hazard Statement modified from [H410 Very toxic to aquatic life with long-lasting effects; H330 Fatal if inhaled; H302 Harmful if swallowed; H318 Causes serious eye damage; H317 May cause an allergic skin reaction; H335 May cause respiratory irritation; H373 May cause damage to organs through prolonged or repeated exposure] to [H410 Very toxic to aquatic life with long-lasting effects; H330 Fatal if inhaled; H302 Harmful if swallowed; H318 Causes serious eye damage; H317 May cause an allergic skin reaction; H335 May cause respiratory irritation; H373 May cause damage to organs through prolonged or repeated exposure; H315 Causes skin irritation] |
| 30/04/2021 |
CutOffs modified from [] to [M = 100 (acute)] Synonym modified from [ zinc bis dimethyldithiocarbamate; Zinc, bis(dimethylcarbamodithioato-S,S')-, (T-4)-] to [zinc bis dimethyldithiocarbamate; Zinc, bis(dimethylcarbamodithioato-S,S')-, (T-4)-] Hazard Category modified from [HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1, HC060:Acute toxicity – category 2, HC062:Acute toxicity – category 4, HC085:Eye damage – category 1, HC092:Skin sensitisation – category 1, HC110:Specific target organ toxicity (single exposure) – category 3, HC112:Specific target organ toxicity (repeated exposure) – category 2] to [HC065:Acute toxicity (inhalation) - category 2, HC072:Acute toxicity (ingestion) - category 4, HC085:Eye damage – category 1, HC092:Skin sensitisation – category 1, HC110:Specific target organ toxicity (single exposure) – category 3, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1] Pictogram modified from [GHS06,GHS05,GHS08,GHS09] to [GHS05,GHS06,GHS08,GHS09] |
| 25/06/2018 |
Hazard Category modified from [HC062:Acute toxicity – category 4, HC060:Acute toxicity – category 2, HC081:Skin corrosion – category 1B, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC092:Skin sensitisation – category 1, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1] to [HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1, HC060:Acute toxicity – category 2, HC062:Acute toxicity – category 4, HC085:Eye damage – category 1, HC092:Skin sensitisation – category 1, HC110:Specific target organ toxicity (single exposure) – category 3, HC112:Specific target organ toxicity (repeated exposure) – category 2] Hazard Statement modified from [H302 Harmful if swallowed; H330 Fatal if inhaled; H314 Causes severe skin burns and eye damage; H373 May cause damage to organs through prolonged or repeated exposure; H317 May cause an allergic skin reaction; H410 Very toxic to aquatic life with long-lasting effects] to [H410 Very toxic to aquatic life with long-lasting effects; H330 Fatal if inhaled; H302 Harmful if swallowed; H318 Causes serious eye damage; H317 May cause an allergic skin reaction; H335 May cause respiratory irritation; H373 May cause damage to organs through prolonged or repeated exposure] |
| 09/05/2018 |
Synonym modified from [ zinc bis dimethyldithiocarbamate] to [ zinc bis dimethyldithiocarbamate; Zinc, bis(dimethylcarbamodithioato-S,S')-, (T-4)-] Hazard Category modified from [HC060:Acute toxicity – category 2, HC062:Acute toxicity – category 4, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC110:Specific target organ toxicity (single exposure) – category 3, HC092:Skin sensitisation – category 1, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1, HC085:Eye damage – category 1] to [HC062:Acute toxicity – category 4, HC060:Acute toxicity – category 2, HC081:Skin corrosion – category 1B, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC092:Skin sensitisation – category 1, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1] Pictogram modified from [GHS06,GHS08,GHS05,GHS09] to [GHS06,GHS05,GHS08,GHS09] Hazard Statement modified from [H330 Fatal if inhaled; H302 Harmful if swallowed; H373 May cause damage to organs through prolonged or repeated exposure; H335 May cause respiratory irritation; H318 Causes serious eye damage; H317 May cause an allergic skin reaction; H410 Very toxic to aquatic life with long-lasting effects] to [H302 ; H330 ; H314 ; H373 ; H317 ; H410 ] Sources modified from [EU] to [N,EU] |
| 25/11/2016 |
Hazard Category modified from [HC060:Acute toxicity – category 2, HC062:Acute toxicity – category 4, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC110:Specific target organ toxicity (single exposure) – category 3, HC092:Skin sensitisation – category 1, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1] to [HC060:Acute toxicity – category 2, HC062:Acute toxicity – category 4, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC110:Specific target organ toxicity (single exposure) – category 3, HC092:Skin sensitisation – category 1, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1, HC085:Eye damage – category 1] |
| 23/06/2016 | Chemical Added |