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| Cas Number | 14324-55-1 |
| Chemical Name | zinc bis(diethyldithiocarbamate) |
| Chemical Synonym |
Zinc, bis(diethylcarbamodithioato-S,S')-, (T-4)- |
| Hazard Category |
Hazardous to the aquatic environment (acute) – category 1 Hazardous to the aquatic environment (chronic) – category 1 Skin sensitisation – category 1 Specific target organ toxicity (repeated exposure) – category 2 Skin irritation – category 2 Specific target organ toxicity (single exposure) – category 3 Acute toxicity (ingestion) - category 4 Eye irritation – category 2A |
| Hazard Statement |
H410 (Very toxic to aquatic life with long-lasting effects) H317 (May cause an allergic skin reaction) H373 (May cause damage to organs through prolonged or repeated exposure) H315 (Causes skin irritation) H335 (May cause respiratory irritation) H302 (Harmful if swallowed) H319 (Causes serious eye irritation) |
| Pictogram |
GHS08 (Health Hazard) 
GHS09 (Environment) 
GHS07 (Exclamation Mark) |
| Signal Word | Warning |
| Cut-offs | |
| Notes |
8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.) |
| Sources |
N (The classification information for this entry was provided by the National Industrial Chemical Notification and Assessment Scheme) EU (Classification information for chemical is taken from the European Union’s Classification, Labelling and Packaging (CLP) Regulation.) |
Hazardous Chemical History
| Date | Description |
|---|---|
| 11/04/2022 |
Signal Word modified from [Danger] to [Warning] Hazard Category modified from [HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1, HC092:Skin sensitisation – category 1, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC083:Skin irritation – category 2, HC110:Specific target organ toxicity (single exposure) – category 3, HC085:Eye damage – category 1, HC072:Acute toxicity (ingestion) - category 4, HC065:Acute toxicity (inhalation) - category 2] to [HC072:Acute toxicity (ingestion) - category 4, HC083:Skin irritation – category 2, HC087:Eye irritation – category 2A, HC092:Skin sensitisation – category 1, HC110:Specific target organ toxicity (single exposure) – category 3, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1] Pictogram modified from [GHS08,GHS09,GHS05,GHS06] to [GHS07,GHS08,GHS09] Hazard Statement modified from [H410 Very toxic to aquatic life with long-lasting effects; H317 May cause an allergic skin reaction; H373 May cause damage to organs through prolonged or repeated exposure; H315 Causes skin irritation; H335 May cause respiratory irritation; H318 Causes serious eye damage; H302 Harmful if swallowed; H330 Fatal if inhaled] to [H410 Very toxic to aquatic life with long-lasting effects; H317 May cause an allergic skin reaction; H373 May cause damage to organs through prolonged or repeated exposure; H315 Causes skin irritation; H335 May cause respiratory irritation; H302 Harmful if swallowed; H319 Causes serious eye irritation] |
| 08/04/2022 |
Signal Word modified from [Warning] to [Danger] Hazard Category modified from [HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1, HC062:Acute toxicity – category 4, HC085:Eye damage – category 1, HC092:Skin sensitisation – category 1, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC083:Skin irritation – category 2, HC110:Specific target organ toxicity (single exposure) – category 3, HC086:Eye irritation – category 2] to [HC065:Acute toxicity (inhalation) - category 2, HC072:Acute toxicity (ingestion) - category 4, HC083:Skin irritation – category 2, HC085:Eye damage – category 1, HC092:Skin sensitisation – category 1, HC110:Specific target organ toxicity (single exposure) – category 3, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1] Pictogram modified from [GHS08,GHS09,GHS07] to [GHS05,GHS06,GHS08,GHS09] Hazard Statement modified from [H410 Very toxic to aquatic life with long-lasting effects; H302 Harmful if swallowed; H317 May cause an allergic skin reaction; H373 May cause damage to organs through prolonged or repeated exposure; H315 Causes skin irritation; H335 May cause respiratory irritation; H319 Causes serious eye irritation] to [H410 Very toxic to aquatic life with long-lasting effects; H317 May cause an allergic skin reaction; H373 May cause damage to organs through prolonged or repeated exposure; H315 Causes skin irritation; H335 May cause respiratory irritation; H318 Causes serious eye damage; H302 Harmful if swallowed; H330 Fatal if inhaled] |
| 19/07/2019 |
Signal Word modified from [Danger] to [Warning] Hazard Category modified from [HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1, HC062:Acute toxicity – category 4, HC081:Skin corrosion – category 1B, HC085:Eye damage – category 1, HC092:Skin sensitisation – category 1, HC112:Specific target organ toxicity (repeated exposure) – category 2] to [HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1, HC062:Acute toxicity – category 4, HC085:Eye damage – category 1, HC092:Skin sensitisation – category 1, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC083:Skin irritation – category 2, HC110:Specific target organ toxicity (single exposure) – category 3, HC086:Eye irritation – category 2] Pictogram modified from [GHS05,GHS08,GHS09,GHS07] to [GHS07,GHS08,GHS09] Hazard Statement modified from [H410 Very toxic to aquatic life with long-lasting effects; H302 Harmful if swallowed; H314 Causes severe skin burns and eye damage; H317 May cause an allergic skin reaction; H373 May cause damage to organs through prolonged or repeated exposure] to [H410 Very toxic to aquatic life with long-lasting effects; H302 Harmful if swallowed; H317 May cause an allergic skin reaction; H373 May cause damage to organs through prolonged or repeated exposure; H315 Causes skin irritation; H335 May cause respiratory irritation; H319 Causes serious eye irritation] |
| 25/06/2018 |
Hazard Category modified from [HC062:Acute toxicity – category 4, HC060:Acute toxicity – category 2, HC081:Skin corrosion – category 1B, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC092:Skin sensitisation – category 1, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1] to [HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1, HC062:Acute toxicity – category 4, HC081:Skin corrosion – category 1B, HC085:Eye damage – category 1, HC092:Skin sensitisation – category 1, HC112:Specific target organ toxicity (repeated exposure) – category 2] Pictogram modified from [GHS06,GHS05,GHS08,GHS09] to [GHS05,GHS08,GHS09,GHS07] Hazard Statement modified from [H302 Harmful if swallowed; H330 Fatal if inhaled; H314 Causes severe skin burns and eye damage; H373 May cause damage to organs through prolonged or repeated exposure; H317 May cause an allergic skin reaction; H410 Very toxic to aquatic life with long-lasting effects] to [H410 Very toxic to aquatic life with long-lasting effects; H302 Harmful if swallowed; H314 Causes severe skin burns and eye damage; H317 May cause an allergic skin reaction; H373 May cause damage to organs through prolonged or repeated exposure] |
| 09/05/2018 |
Signal Word modified from [Warning] to [Danger] Synonym modified from [] to [Zinc, bis(diethylcarbamodithioato-S,S')-, (T-4)-] Hazard Category modified from [HC062:Acute toxicity – category 4, HC086:Eye irritation – category 2, HC110:Specific target organ toxicity (single exposure) – category 3, HC083:Skin irritation – category 2, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1, HC092:Skin sensitisation – category 1] to [HC062:Acute toxicity – category 4, HC060:Acute toxicity – category 2, HC081:Skin corrosion – category 1B, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC092:Skin sensitisation – category 1, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1] Pictogram modified from [GHS07,GHS09] to [GHS06,GHS05,GHS08,GHS09] Hazard Statement modified from [H302 Harmful if swallowed; H319 Causes serious eye irritation; H335 May cause respiratory irritation; H315 Causes skin irritation; H317 May cause an allergic skin reaction; H410 Very toxic to aquatic life with long-lasting effects] to [H302 ; H330 ; H314 ; H373 ; H317 ; H410 ] Sources modified from [EU] to [N,EU] |
| 25/11/2016 |
Hazard Category modified from [HC062:Acute toxicity – category 4, HC086:Eye irritation – category 2, HC110:Specific target organ toxicity (single exposure) – category 3, HC083:Skin irritation – category 2, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1] to [HC062:Acute toxicity – category 4, HC086:Eye irritation – category 2, HC110:Specific target organ toxicity (single exposure) – category 3, HC083:Skin irritation – category 2, HC115:Hazardous to the aquatic environment (acute) – category 1, HC118:Hazardous to the aquatic environment (chronic) – category 1, HC092:Skin sensitisation – category 1] |
| 23/06/2016 | Chemical Added |