Hazardous Chemical Information System (HCIS)



Hazardous Chemical Details

Cas Number 136-23-2
Chemical Name zinc bis(dibutyldithiocarbamate)
Chemical Synonym Zinc, bis(dibutylcarbamodithioato-S,S')-, (T-4)-
Hazard Category Hazardous to the aquatic environment (acute) – category 1
Hazardous to the aquatic environment (chronic) – category 1
Skin sensitisation – category 1
Specific target organ toxicity (single exposure) – category 3
Hazard Statement H410 (Very toxic to aquatic life with long-lasting effects)
H317 (May cause an allergic skin reaction)
H335 (May cause respiratory irritation)
Pictogram Pictogram of Environment GHS09 (Environment)
Pictogram of Exclamation Mark GHS07 (Exclamation Mark)
Signal Word Warning
Cut-offs
Notes 8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.)
Sources N (The classification information for this entry was provided by the National Industrial Chemical Notification and Assessment Scheme)
EU (Classification information for chemical is taken from the European Union’s Classification, Labelling and Packaging (CLP) Regulation.)

Hazardous Chemical History

Date Description
25/06/2018 Signal Word modified from
[Danger]
to
[Warning]
Hazard Category modified from
[HC062:Acute toxicity – category 4,
HC060:Acute toxicity – category 2,
HC081:Skin corrosion – category 1B,
HC112:Specific target organ toxicity (repeated exposure) – category 2,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

to
[HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1,
HC092:Skin sensitisation – category 1,
HC110:Specific target organ toxicity (single exposure) – category 3]

Pictogram modified from
[GHS06,GHS05,GHS08,GHS09]
to
[GHS09,GHS07]
Hazard Statement modified from
[H302 Harmful if swallowed;
H330 Fatal if inhaled;
H314 Causes severe skin burns and eye damage;
H373 May cause damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction;
H410 Very toxic to aquatic life with long-lasting effects]
to
[H410 Very toxic to aquatic life with long-lasting effects;
H317 May cause an allergic skin reaction;
H335 May cause respiratory irritation]
09/05/2018 Signal Word modified from
[Warning]
to
[Danger]
Synonym modified from
[]
to
[Zinc, bis(dibutylcarbamodithioato-S,S')-, (T-4)-]
Hazard Category modified from
[HC086:Eye irritation – category 2,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC083:Skin irritation – category 2,
HC092:Skin sensitisation – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1]

to
[HC062:Acute toxicity – category 4,
HC060:Acute toxicity – category 2,
HC081:Skin corrosion – category 1B,
HC112:Specific target organ toxicity (repeated exposure) – category 2,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

Pictogram modified from
[GHS07,GHS09]
to
[GHS06,GHS05,GHS08,GHS09]
Hazard Statement modified from
[H319 Causes serious eye irritation;
H335 May cause respiratory irritation;
H315 Causes skin irritation;
H317 May cause an allergic skin reaction;
H410 Very toxic to aquatic life with long-lasting effects]
to
[H302 ;
H330 ;
H314 ;
H373 ;
H317 ;
H410 ]
Sources modified from
[EU]
to
[N,EU]
25/11/2016 Hazard Category modified from
[HC086:Eye irritation – category 2,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC083:Skin irritation – category 2,
HC092:Skin sensitisation – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

to
[HC086:Eye irritation – category 2,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC083:Skin irritation – category 2,
HC092:Skin sensitisation – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1]
23/06/2016 Chemical Added