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Hazardous Chemical Information System (HCIS)




Hazardous Chemical Details

Cas Number 97-74-5
Chemical Name tetramethylthiuram monosulphide
Chemical Synonym tetramethylthiuram monosulfide
Thiodicarbonic diamide ([(H2N)C(S)]2S), tetramethyl-
Hazard Category Acute toxicity (ingestion) - category 4
Acute toxicity (inhalation) - category 4
Germ cell mutagenicity – category 2
Eye irritation – category 2A
Skin irritation – category 2
Specific target organ toxicity (repeated exposure) – category 2
Skin sensitisation – category 1
Hazard Statement H302 (Harmful if swallowed)
H341 (Suspected of causing genetic defects)
H319 (Causes serious eye irritation)
H315 (Causes skin irritation)
H373 (May cause damage to organs through prolonged or repeated exposure)
H317 (May cause an allergic skin reaction)
H332 (Harmful if inhaled)
Pictogram Pictogram of Exclamation Mark GHS07 (Exclamation Mark)
Pictogram of Health Hazard GHS08 (Health Hazard)
Signal Word Warning
Cut-offs
Notes 8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.)
Sources N (The classification information for this entry was provided by the National Industrial Chemical Notification and Assessment Scheme)

Hazardous Chemical History

Date Description
09/03/2021 Hazard Category modified from
[HC072:Acute toxicity (ingestion) - category 4,
HC067:Acute toxicity (inhalation) - category 4,
HC098:Germ cell mutagenicity – category 2]

to
[HC067:Acute toxicity (inhalation) - category 4,
HC072:Acute toxicity (ingestion) - category 4,
HC083:Skin irritation – category 2,
HC087:Eye irritation – category 2A,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC112:Specific target organ toxicity (repeated exposure) – category 2]

Hazard Statement modified from
[H302 Harmful if swallowed;
H331 Toxic if inhaled;
H341 Suspected of causing genetic defects;
H319 Causes serious eye irritation;
H315 Causes skin irritation;
H373 May cause damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction]
to
[H302 Harmful if swallowed;
H341 Suspected of causing genetic defects;
H319 Causes serious eye irritation;
H315 Causes skin irritation;
H373 May cause damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction;
H332 Harmful if inhaled]
09/03/2021 Synonym modified from
[tetramethylthiuram monosulfide ;
Thiodicarbonic diamide ([(H2N)C(S)]2S), tetramethyl-]
to
[tetramethylthiuram monosulfide;
Thiodicarbonic diamide ([(H2N)C(S)]2S), tetramethyl-]
Hazard Category modified from
[HC072:Acute toxicity (ingestion) - category 4,
HC067:Acute toxicity (inhalation) - category 4,
HC098:Germ cell mutagenicity – category 2,
HC119:Hazardous to the aquatic environment (chronic) – category 2]

to
[HC067:Acute toxicity (inhalation) - category 4,
HC072:Acute toxicity (ingestion) - category 4,
HC098:Germ cell mutagenicity – category 2]

Pictogram modified from
[GHS07,GHS08,GHS09]
to
[GHS07,GHS08]
Hazard Statement modified from
[H302 Harmful if swallowed;
H331 Toxic if inhaled;
H341 Suspected of causing genetic defects;
H319 Causes serious eye irritation;
H315 Causes skin irritation;
H373 May cause damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction;
H411 Toxic to aquatic life with long-lasting effects]
to
[H302 Harmful if swallowed;
H331 Toxic if inhaled;
H341 Suspected of causing genetic defects;
H319 Causes serious eye irritation;
H315 Causes skin irritation;
H373 May cause damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction]
Sources modified from
[N,EU]
to
[N]
09/03/2021 Synonym modified from
[tetramethylthiuram monosulfide;
Thiodicarbonic diamide ([(H2N)C(S)]2S), tetramethyl-]
to
[tetramethylthiuram monosulfide ;
Thiodicarbonic diamide ([(H2N)C(S)]2S), tetramethyl-]
Hazard Category modified from
[HC072:Acute toxicity (ingestion) - category 4,
HC067:Acute toxicity (inhalation) - category 4,
HC098:Germ cell mutagenicity – category 2]

to
[HC067:Acute toxicity (inhalation) - category 4,
HC072:Acute toxicity (ingestion) - category 4,
HC098:Germ cell mutagenicity – category 2,
HC119:Hazardous to the aquatic environment (chronic) – category 2]

Pictogram modified from
[GHS07,GHS08]
to
[GHS07,GHS08,GHS09]
Hazard Statement modified from
[H302 Harmful if swallowed;
H331 Toxic if inhaled;
H341 Suspected of causing genetic defects;
H319 Causes serious eye irritation;
H315 Causes skin irritation;
H373 May cause damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction]
to
[H302 Harmful if swallowed;
H331 Toxic if inhaled;
H341 Suspected of causing genetic defects;
H319 Causes serious eye irritation;
H315 Causes skin irritation;
H373 May cause damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction;
H411 Toxic to aquatic life with long-lasting effects]
Sources modified from
[N]
to
[N,EU]
09/03/2021 Synonym modified from
[tetramethylthiuram monosulfide ;
Thiodicarbonic diamide ([(H2N)C(S)]2S), tetramethyl-]
to
[tetramethylthiuram monosulfide;
Thiodicarbonic diamide ([(H2N)C(S)]2S), tetramethyl-]
Hazard Category modified from
[HC072:Acute toxicity (ingestion) - category 4,
HC067:Acute toxicity (inhalation) - category 4,
HC098:Germ cell mutagenicity – category 2,
HC119:Hazardous to the aquatic environment (chronic) – category 2]

to
[HC067:Acute toxicity (inhalation) - category 4,
HC072:Acute toxicity (ingestion) - category 4,
HC098:Germ cell mutagenicity – category 2]

Pictogram modified from
[GHS07,GHS08,GHS09]
to
[GHS07,GHS08]
Hazard Statement modified from
[H302 Harmful if swallowed;
H331 Toxic if inhaled;
H341 Suspected of causing genetic defects;
H319 Causes serious eye irritation;
H315 Causes skin irritation;
H373 May cause damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction;
H411 Toxic to aquatic life with long-lasting effects]
to
[H302 Harmful if swallowed;
H331 Toxic if inhaled;
H341 Suspected of causing genetic defects;
H319 Causes serious eye irritation;
H315 Causes skin irritation;
H373 May cause damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction]
Sources modified from
[N,EU]
to
[N]
09/03/2021 Synonym modified from
[tetramethylthiuram monosulfide]
to
[tetramethylthiuram monosulfide ;
Thiodicarbonic diamide ([(H2N)C(S)]2S), tetramethyl-]
Hazard Category modified from
[HC062:Acute toxicity – category 4,
HC092:Skin sensitisation – category 1,
HC119:Hazardous to the aquatic environment (chronic) – category 2]

to
[HC067:Acute toxicity (inhalation) - category 4,
HC072:Acute toxicity (ingestion) - category 4,
HC098:Germ cell mutagenicity – category 2,
HC119:Hazardous to the aquatic environment (chronic) – category 2]

Pictogram modified from
[GHS07,GHS09]
to
[GHS07,GHS08,GHS09]
Hazard Statement modified from
[H302 Harmful if swallowed;
H317 May cause an allergic skin reaction;
H411 Toxic to aquatic life with long-lasting effects]
to
[H302 Harmful if swallowed;
H331 Toxic if inhaled;
H341 Suspected of causing genetic defects;
H319 Causes serious eye irritation;
H315 Causes skin irritation;
H373 May cause damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction;
H411 Toxic to aquatic life with long-lasting effects]
Sources modified from
[EU]
to
[N,EU]
26/07/2019 Synonym modified from
[]
to
[tetramethylthiuram monosulfide]
23/06/2016 Chemical Added



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