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Hazardous Chemical Information System (HCIS)

Hazardous Chemical Details

Cas Number	10332-33-9
Chemical Name	perboric acid (HBO(O2)), sodium salt, monohydrate
Chemical Synonym	sodium perborate perboric acid (HBO(O2)), sodium salt, monohydrate [containing = 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 µm] perboric acid (HBO(O2)), sodium salt, monohydrate [containing < 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 µm] sodium perborate monohydrate
Hazard Category	Oxidising solid – category 3 Reproductive toxicity – category 1B Eye damage – category 1 Specific target organ toxicity (single exposure) – category 3 Acute toxicity (inhalation) - category 3 Acute toxicity (ingestion) - category 4
Hazard Statement	H272 (May intensify fire; oxidizer) H360Df (May damage the unborn child. Suspected of damaging fertility) H335 (May cause respiratory irritation) H318 (Causes serious eye damage) H331 (Toxic if inhaled) H302 (Harmful if swallowed)
Pictogram	GHS03 (Flame Over Circle) GHS06 (Skull and Crossbones) GHS05 (Corrosion) GHS08 (Health Hazard)
Signal Word	Danger
Cut-offs	Reproductive toxicity - category 1B (H360Df): concentration >= 9 %; Reproductive toxicity - category 1B (H360D): 6.5 % <= concentration < 9 %; Eye Damage - category 1 (H318): concentration >= 22 %; Eye irritation - category 2 (H319): 14 % <= concentration < 22 %
Notes	8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.) 17 (Generic cut off concentrations also apply to this chemical in addition to the specific cut off concentration(s) above. Refer to the generic cut off concentration table on the Reference Information page of HCIS (http://hcis.safeworkaustralia.gov.au/UserGuide).)
Sources	EU (Classification information for chemical is taken from the European Union’s Classification, Labelling and Packaging (CLP) Regulation.) N (The classification information for this entry was provided by the National Industrial Chemical Notification and Assessment Scheme)

Hazardous Chemical History

Date	Description
30/04/2021	Name modified from [perboric acid (HBO(O2)), sodium salt, monohydrate [containing ≥ 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]] to [perboric acid (HBO(O2)), sodium salt, monohydrate] Synonym modified from [sodium peroxoborate [containing = 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 µm]] to [sodium perborate; perboric acid (HBO(O2)), sodium salt, monohydrate [containing ≥ 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]; perboric acid (HBO(O2)), sodium salt, monohydrate [containing < 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]; sodium perborate monohydrate] Hazard Category modified from [HC046:Oxidising solid – category 3, HC105:Reproductive toxicity – category 1B, HC085:Eye damage – category 1, HC110:Specific target organ toxicity (single exposure) – category 3, HC066:Acute toxicity (inhalation) - category 3, HC072:Acute toxicity (ingestion) - category 4] to [HC046:Oxidising solid – category 3, HC066:Acute toxicity (inhalation) - category 3, HC072:Acute toxicity (ingestion) - category 4, HC085:Eye damage – category 1, HC105:Reproductive toxicity – category 1B, HC110:Specific target organ toxicity (single exposure) – category 3] Pictogram modified from [GHS03,GHS06,GHS05,GHS08] to [GHS03,GHS05,GHS06,GHS08] Sources modified from [EU] to [EU,N]
30/04/2021	Synonym modified from [sodium peroxoborate [containing = 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 µm]] to [sodium peroxoborate [containing ≥ 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 µm]] Hazard Category modified from [HC046:Oxidising solid – category 3, HC105:Reproductive toxicity – category 1B, HC085:Eye damage – category 1, HC110:Specific target organ toxicity (single exposure) – category 3, HC066:Acute toxicity (inhalation) - category 3, HC072:Acute toxicity (ingestion) - category 4] to [HC046:Oxidising solid – category 3, HC066:Acute toxicity (inhalation) - category 3, HC072:Acute toxicity (ingestion) - category 4, HC085:Eye damage – category 1, HC105:Reproductive toxicity – category 1B, HC110:Specific target organ toxicity (single exposure) – category 3] Pictogram modified from [GHS03,GHS06,GHS05,GHS08] to [GHS03,GHS05,GHS06,GHS08]
30/04/2021	Name modified from [perboric acid (HBO(O2)), sodium salt, monohydrate[containing ≥ 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]] to [perboric acid (HBO(O2)), sodium salt, monohydrate [containing ≥ 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]] Synonym modified from [] to [sodium peroxoborate [containing ≥ 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]] Hazard Category modified from [HC046:Oxidising solid – category 3, HC105:Reproductive toxicity – category 1B, HC085:Eye damage – category 1, HC110:Specific target organ toxicity (single exposure) – category 3, HC066:Acute toxicity (inhalation) - category 3, HC072:Acute toxicity (ingestion) - category 4] to [HC046:Oxidising solid – category 3, HC066:Acute toxicity (inhalation) - category 3, HC072:Acute toxicity (ingestion) - category 4, HC085:Eye damage – category 1, HC105:Reproductive toxicity – category 1B, HC110:Specific target organ toxicity (single exposure) – category 3] Pictogram modified from [GHS03,GHS06,GHS05,GHS08] to [GHS03,GHS05,GHS06,GHS08]
30/04/2021	CutOffs modified from [] to [ Reproductive toxicity - category 1B (H360Df): concentration >= 9 %; Reproductive toxicity - category 1B (H360D): 6.5 % <= concentration < 9 %; Eye Damage - category 1 (H318): concentration >= 22 %; Eye irritation - category 2 (H319): 14 % <= concentration < 22 % ] Hazard Category modified from [HC046:Oxidising solid – category 3, HC105:Reproductive toxicity – category 1B, HC061:Acute toxicity – category 3, HC062:Acute toxicity – category 4, HC085:Eye damage – category 1, HC110:Specific target organ toxicity (single exposure) – category 3] to [HC046:Oxidising solid – category 3, HC066:Acute toxicity (inhalation) - category 3, HC072:Acute toxicity (ingestion) - category 4, HC085:Eye damage – category 1, HC105:Reproductive toxicity – category 1B, HC110:Specific target organ toxicity (single exposure) – category 3] Pictogram modified from [GHS03,GHS06,GHS05,GHS08] to [GHS03,GHS05,GHS06,GHS08] Hazard Statement modified from [H272 May intensify fire; oxidizer; H360Df May damage the unborn child. Suspected of damaging fertility; H331 Toxic if inhaled; H302 Harmful if swallowed; H335 May cause respiratory irritation; H318 Causes serious eye damage] to [H272 May intensify fire; oxidizer; H360Df May damage the unborn child. Suspected of damaging fertility; H335 May cause respiratory irritation; H318 Causes serious eye damage; H331 Toxic if inhaled; H302 Harmful if swallowed] Notes modified from [8 ] to [8 ,17 ]
25/11/2016	Hazard Category modified from [HC046:Oxidising solid – category 3, HC105:Reproductive toxicity – category 1B, HC061:Acute toxicity – category 3, HC062:Acute toxicity – category 4, HC085:Eye damage – category 1] to [HC046:Oxidising solid – category 3, HC105:Reproductive toxicity – category 1B, HC061:Acute toxicity – category 3, HC062:Acute toxicity – category 4, HC085:Eye damage – category 1, HC110:Specific target organ toxicity (single exposure) – category 3]
23/06/2016	Chemical Added