Hazardous Chemical Information System (HCIS)



Hazardous Chemical Details

Cas Number 10332-33-9
Chemical Name perboric acid (HBO(O2)), sodium salt, monohydrate [containing < 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
Chemical Synonym sodium peroxoborate [containing < 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 µm]
Hazard Category Oxidising solid – category 3
Acute toxicity – category 4
Eye damage – category 1
Reproductive toxicity – category 1B
Specific target organ toxicity (single exposure) – category 3
Hazard Statement H272 (May intensify fire; oxidizer)
H302 (Harmful if swallowed)
H318 (Causes serious eye damage)
H335 (May cause respiratory irritation)
H360Df (May damage the unborn child. Suspected of damaging fertility.)
Pictogram Pictogram of Flame Over Circle GHS03 (Flame Over Circle)
Pictogram of Corrosion GHS05 (Corrosion)
Pictogram of Health Hazard GHS08 (Health Hazard)
Pictogram of Exclamation Mark GHS07 (Exclamation Mark)
Signal Word Danger
Cut-offs

Reproductive toxicity - category 1B (H360Df): concentration >= 9 %;
Reproductive toxicity - category 1B (H360D): 6.5 % <= concentration < 9 %;
Eye Damage. - category 1 (H318): concentration >= 22 %;
Eye irritation - category 2 (H319): 14 % <= concentration < 22 %

Notes 8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.)
17 (Generic cut off concentrations also apply to this chemical in addition to the specific cut off concentration(s) above. Refer to the generic cut off concentration table on the Reference Information page of HCIS (http://hcis.safeworkaustralia.gov.au/UserGuide).)
Sources EU (Classification information for chemical is taken from the European Union’s Classification, Labelling and Packaging (CLP) Regulation.)

Hazardous Chemical History

Date Description
28/04/2021 Chemical Deleted
28/04/2021 CutOffs modified from
[Reproductive toxicity - category 1B (H360Df): concentration >= 9 %;
Reproductive toxicity - category 1B (H360D): 6.5 % <= concentration < 9 %;
Eye Damage. - category 1 (H318): concentration >= 22 %;
Eye irritation - category 2 (H319): 14 % <= concentration < 22 %]
to
[

Reproductive toxicity - category 1B (H360Df): concentration >= 9 %;
Reproductive toxicity - category 1B (H360D): 6.5 % <= concentration < 9 %;
Eye Damage. - category 1 (H318): concentration >= 22 %;
Eye irritation - category 2 (H319): 14 % <= concentration < 22 %

]
Synonym modified from
[]
to
[sodium peroxoborate [containing < 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]]
Pictogram modified from
[GHS03,GHS05,GHS08,GHS07]
to
[GHS03,GHS05,GHS07,GHS08]
Hazard Statement modified from
[H272 May intensify fire;
H302 oxidizer;
H318 Harmful if swallowed;
H335 Causes serious eye damage;
H360Df May cause respiratory irritation]
to
[H272 May intensify fire; oxidizer;
H302 Harmful if swallowed;
H318 Causes serious eye damage;
H335 May cause respiratory irritation;
H360Df May damage the unborn child. Suspected of damaging fertility. ]
Sources modified from
[N,EU]
to
[EU]
28/04/2021 CutOffs modified from
[]
to
[Reproductive toxicity - category 1B (H360Df): concentration >= 9 %;
Reproductive toxicity - category 1B (H360D): 6.5 % <= concentration < 9 %;
Eye Damage. - category 1 (H318): concentration >= 22 %;
Eye irritation - category 2 (H319): 14 % <= concentration < 22 %]
Pictogram modified from
[GHS03,GHS05,GHS08,GHS07]
to
[GHS03,GHS05,GHS07,GHS08]
Hazard Statement modified from
[H272 May intensify fire; oxidizer;
H302 Harmful if swallowed;
H318 Causes serious eye damage;
H335 May cause respiratory irritation;
H360Df May damage the unborn child. Suspected of damaging fertility]
to
[H272 May intensify fire;
H302 oxidizer;
H318 Harmful if swallowed;
H335 Causes serious eye damage;
H360Df May cause respiratory irritation]
Notes modified from
[8 ]
to
[8 , 17 ]
30/09/2019 Name modified from
[perboric acid (HBO(O2)), sodium salt, monohydrate[containing < 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]]
to
[perboric acid (HBO(O2)), sodium salt, monohydrate [containing < 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]]
Hazard Category modified from
[HC046:Oxidising solid – category 3,
HC062:Acute toxicity – category 4,
HC060:Acute toxicity – category 2,
HC085:Eye damage – category 1,
HC105:Reproductive toxicity – category 1B,
HC110:Specific target organ toxicity (single exposure) – category 3]

to
[HC046:Oxidising solid – category 3,
HC062:Acute toxicity – category 4,
HC085:Eye damage – category 1,
HC105:Reproductive toxicity – category 1B,
HC110:Specific target organ toxicity (single exposure) – category 3]

Pictogram modified from
[GHS03,GHS06,GHS05,GHS08]
to
[GHS03,GHS05,GHS07,GHS08]
Hazard Statement modified from
[H272 May intensify fire; oxidizer;
H302 Harmful if swallowed;
H330 Fatal if inhaled;
H332 Harmful if inhaled;
H318 Causes serious eye damage;
H335 May cause respiratory irritation;
H360Df May damage the unborn child. Suspected of damaging fertility]
to
[H272 May intensify fire; oxidizer;
H302 Harmful if swallowed;
H318 Causes serious eye damage;
H335 May cause respiratory irritation;
H360Df May damage the unborn child. Suspected of damaging fertility]
09/05/2018 Hazard Category modified from
[HC046:Oxidising solid – category 3,
HC105:Reproductive toxicity – category 1B,
HC062:Acute toxicity – category 4,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC085:Eye damage – category 1]

to
[HC046:Oxidising solid – category 3,
HC062:Acute toxicity – category 4,
HC060:Acute toxicity – category 2,
HC085:Eye damage – category 1,
HC105:Reproductive toxicity – category 1B,
HC110:Specific target organ toxicity (single exposure) – category 3]

Pictogram modified from
[GHS03,GHS05,GHS08,GHS07]
to
[GHS03,GHS06,GHS05,GHS08]
Hazard Statement modified from
[H272 May intensify fire; oxidizer;
H360Df May damage the unborn child. Suspected of damaging fertility;
H302 Harmful if swallowed;
H335 May cause respiratory irritation;
H318 Causes serious eye damage]
to
[H272 ;
H302 ;
H330 ;
H332 ;
H318 ;
H335 ;
H360Df ]
Sources modified from
[EU]
to
[N,EU]
23/06/2016 Chemical Added