Hazardous Chemical Information System (HCIS)



Hazardous Chemical Details

Cas Number 75113-37-0
Chemical Name dibutyltin hydrogen borate
Chemical Synonym 1,3-Dioxa-2-stanna-4-boracyclobutane, 2,2-dibutyl-4-hydroxy-
1,3,2,4-dioxastannaboretane,2,2-dibutyl-4-hydroxydibutyltin hydrogen borate
Hazard Category Skin corrosion – category 1B
Skin sensitisation – category 1
Germ cell mutagenicity – category 2
Reproductive toxicity – category 1B
Specific target organ toxicity (repeated exposure) – category 1
Hazardous to the aquatic environment (acute) – category 1
Hazardous to the aquatic environment (chronic) – category 1
Acute toxicity (inhalation) - category 2
Acute toxicity (ingestion) - category 3
Acute toxicity (dermal) - category 4
Hazard Statement H314 (Causes severe skin burns and eye damage)
H317 (May cause an allergic skin reaction)
H341 (Suspected of causing genetic defects)
H360FD (May damage fertility. May damage the unborn child)
H372 (Causes damage to organs through prolonged or repeated exposure if swallowed)
H410 (Very toxic to aquatic life with long-lasting effects)
H330 (Fatal if inhaled)
H301 (Toxic if swallowed)
H312 (Harmful in contact with skin)
Pictogram Pictogram of Corrosion GHS05 (Corrosion)
Pictogram of Skull and Crossbones GHS06 (Skull and Crossbones)
Pictogram of Health Hazard GHS08 (Health Hazard)
Pictogram of Environment GHS09 (Environment)
Signal Word Danger
Cut-offs
Notes 8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.)
Sources EU (Classification information for chemical is taken from the European Union’s Classification, Labelling and Packaging (CLP) Regulation.)
A (The classification information for this entry was provided by the Australian Industrial Chemicals Introduction Scheme)

Hazardous Chemical History

Date Description
18/08/2021 Synonym modified from
[1,3-Dioxa-2-stanna-4-boracyclobutane, 2,2-dibutyl-4-hydroxy-]
to
[1,3-Dioxa-2-stanna-4-boracyclobutane, 2,2-dibutyl-4-hydroxy-;
1,3,2,4-dioxastannaboretane,2,2-dibutyl-4-hydroxydibutyltin hydrogen borate ]
Hazard Category modified from
[HC081:Skin corrosion – category 1B,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1,
HC065:Acute toxicity (inhalation) - category 2,
HC071:Acute toxicity (ingestion) - category 3,
HC077:Acute toxicity (dermal) - category 4]

to
[HC065:Acute toxicity (inhalation) - category 2,
HC071:Acute toxicity (ingestion) - category 3,
HC077:Acute toxicity (dermal) - category 4,
HC081:Skin corrosion – category 1B,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

Hazard Statement modified from
[H314 Causes severe skin burns and eye damage;
H317 May cause an allergic skin reaction;
H341 Suspected of causing genetic defects;
H360FD May damage fertility. May damage the unborn child;
H372 Causes damage to organs through prolonged or repeated exposure;
H410 Very toxic to aquatic life with long-lasting effects;
H330 Fatal if inhaled;
H301 Toxic if swallowed;
H312 Harmful in contact with skin]
to
[H314 Causes severe skin burns and eye damage;
H317 May cause an allergic skin reaction;
H341 Suspected of causing genetic defects;
H360FD May damage fertility. May damage the unborn child;
H372 Causes damage to organs through prolonged or repeated exposure if swallowed;
H410 Very toxic to aquatic life with long-lasting effects;
H330 Fatal if inhaled;
H301 Toxic if swallowed;
H312 Harmful in contact with skin]
18/08/2021 Hazard Category modified from
[HC060:Acute toxicity – category 2,
HC061:Acute toxicity – category 3,
HC062:Acute toxicity – category 4,
HC081:Skin corrosion – category 1B,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

to
[HC065:Acute toxicity (inhalation) - category 2,
HC071:Acute toxicity (ingestion) - category 3,
HC077:Acute toxicity (dermal) - category 4,
HC081:Skin corrosion – category 1B,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

Hazard Statement modified from
[H330 Fatal if inhaled;
H301 Toxic if swallowed;
H312 Harmful in contact with skin;
H314 Causes severe skin burns and eye damage;
H317 May cause an allergic skin reaction;
H341 Suspected of causing genetic defects;
H360FD May damage fertility. May damage the unborn child;
H372 Causes damage to organs through prolonged or repeated exposure;
H410 Very toxic to aquatic life with long-lasting effects]
to
[H314 Causes severe skin burns and eye damage;
H317 May cause an allergic skin reaction;
H341 Suspected of causing genetic defects;
H360FD May damage fertility. May damage the unborn child;
H372 Causes damage to organs through prolonged or repeated exposure;
H410 Very toxic to aquatic life with long-lasting effects;
H330 Fatal if inhaled;
H301 Toxic if swallowed;
H312 Harmful in contact with skin]
Sources modified from
[N,EU]
to
[EU,A]
09/05/2018 Synonym modified from
[]
to
[1,3-Dioxa-2-stanna-4-boracyclobutane, 2,2-dibutyl-4-hydroxy-]
Hazard Category modified from
[HC105:Reproductive toxicity – category 1B,
HC098:Germ cell mutagenicity – category 2,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC062:Acute toxicity – category 4,
HC085:Eye damage – category 1,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

to
[HC060:Acute toxicity – category 2,
HC061:Acute toxicity – category 3,
HC062:Acute toxicity – category 4,
HC081:Skin corrosion – category 1B,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

Pictogram modified from
[GHS05,GHS08,GHS07,GHS09]
to
[GHS05,GHS06,GHS08,GHS09]
Hazard Statement modified from
[H360FD May damage fertility. May damage the unborn child;
H341 Suspected of causing genetic defects;
H372 Causes damage to organs through prolonged or repeated exposure;
H312 Harmful in contact with skin;
H302 Harmful if swallowed;
H318 Causes serious eye damage;
H317 May cause an allergic skin reaction;
H410 Very toxic to aquatic life with long-lasting effects]
to
[H330 ;
H301 ;
H312 ;
H314 ;
H317 ;
H341 ;
H360FD ;
H372 ;
H410 ]
Sources modified from
[EU]
to
[N,EU]
25/11/2016 Hazard Category modified from
[HC105:Reproductive toxicity – category 1B,
HC098:Germ cell mutagenicity – category 2,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC062:Acute toxicity – category 4,
HC085:Eye damage – category 1,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1]

to
[HC105:Reproductive toxicity – category 1B,
HC098:Germ cell mutagenicity – category 2,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC062:Acute toxicity – category 4,
HC085:Eye damage – category 1,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]
23/06/2016 Chemical Added