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Hazardous Chemical Details

Cas Number 683-18-1
Chemical Name dibutyltin dichloride
Chemical Synonym DBTC
Stannane, dibutyldichloro-
Hazard Category Acute toxicity (inhalation) - category 2
Acute toxicity (ingestion) - category 3
Acute toxicity (dermal) - category 4
Skin corrosion – category 1B
Germ cell mutagenicity – category 2
Reproductive toxicity – category 1B
Specific target organ toxicity (repeated exposure) – category 1
Skin sensitisation – category 1
Hazardous to the aquatic environment (acute) – category 1
Hazardous to the aquatic environment (chronic) – category 1
Hazard Statement H330 (Fatal if inhaled)
H301 (Toxic if swallowed)
H312 (Harmful in contact with skin)
H314 (Causes severe skin burns and eye damage)
H341 (Suspected of causing genetic defects)
H360FD (May damage fertility. May damage the unborn child)
H372 (Causes damage to organs through prolonged or repeated exposure if swallowed)
H317 (May cause an allergic skin reaction)
H410 (Very toxic to aquatic life with long-lasting effects)
Pictogram Pictogram of Corrosion GHS05 (Corrosion)
Pictogram of Skull and Crossbones GHS06 (Skull and Crossbones)
Pictogram of Health Hazard GHS08 (Health Hazard)
Pictogram of Environment GHS09 (Environment)
Signal Word Danger
Cut-offs

Skin corrosion - category 1B (H314): concentration >= 5%;
Skin irritation - category 2 (H315): 0.01% <= concentration < 5%;

M = 10 (acute)
Notes 8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.)
17 (Generic cut off concentrations also apply to this chemical in addition to the specific cut off concentration(s) above. Refer to the generic cut off concentration table on the Reference Information page of HCIS (http://hcis.safeworkaustralia.gov.au/UserGuide).)
Sources EU (Classification information for chemical is taken from the European Union’s Classification, Labelling and Packaging (CLP) Regulation.)
A (The classification information for this entry was provided by the Australian Industrial Chemicals Introduction Scheme)

Hazardous Chemical History

Date Description
08/04/2022 CutOffs modified from
[

Skin corrosion - category 1B (H314): concentration >= 5%;
Skin irritation - category 2 (H315): 0.01% <= concentration < 5%;
Eye damage - category 1 (H318): 3% <= concentration < 5%;
Eye Irritation - category 2 (H319): 0.01% <= concentration <3%;

M = 10 (acute)

]
to
[

Skin corrosion - category 1B (H314): concentration >= 5%;
Skin irritation - category 2 (H315): 0.01% <= concentration < 5%;

M = 10 (acute)

]
Hazard Category modified from
[HC065:Acute toxicity (inhalation) - category 2,
HC071:Acute toxicity (ingestion) - category 3,
HC077:Acute toxicity (dermal) - category 4,
HC081:Skin corrosion – category 1B,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

to
[HC065:Acute toxicity (inhalation) - category 2,
HC071:Acute toxicity (ingestion) - category 3,
HC077:Acute toxicity (dermal) - category 4,
HC081:Skin corrosion – category 1B,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]
08/04/2022 Hazard Category modified from
[HC065:Acute toxicity (inhalation) - category 2,
HC071:Acute toxicity (ingestion) - category 3,
HC077:Acute toxicity (dermal) - category 4,
HC081:Skin corrosion – category 1B,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

to
[HC065:Acute toxicity (inhalation) - category 2,
HC071:Acute toxicity (ingestion) - category 3,
HC077:Acute toxicity (dermal) - category 4,
HC081:Skin corrosion – category 1B,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

Hazard Statement modified from
[H330 Fatal if inhaled;
H301 Toxic if swallowed;
H312 Harmful in contact with skin;
H314 Causes severe skin burns and eye damage;
H341 Suspected of causing genetic defects;
H360FD May damage fertility. May damage the unborn child;
H372 Causes damage to organs through prolonged or repeated exposure if swallowed;
H317 Very toxic to aquatic life with long-lasting effects;
H410 Very toxic to aquatic life with long-lasting effects]
to
[H330 Fatal if inhaled;
H301 Toxic if swallowed;
H312 Harmful in contact with skin;
H314 Causes severe skin burns and eye damage;
H341 Suspected of causing genetic defects;
H360FD May damage fertility. May damage the unborn child;
H372 Causes damage to organs through prolonged or repeated exposure if swallowed;
H317 May cause an allergic skin reaction;
H410 Very toxic to aquatic life with long-lasting effects]
08/04/2022 Hazard Category modified from
[HC065:Acute toxicity (inhalation) - category 2,
HC071:Acute toxicity (ingestion) - category 3,
HC077:Acute toxicity (dermal) - category 4,
HC081:Skin corrosion – category 1B,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

to
[HC065:Acute toxicity (inhalation) - category 2,
HC071:Acute toxicity (ingestion) - category 3,
HC077:Acute toxicity (dermal) - category 4,
HC081:Skin corrosion – category 1B,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

Hazard Statement modified from
[H330 Fatal if inhaled;
H301 Toxic if swallowed;
H312 Harmful in contact with skin;
H314 Causes severe skin burns and eye damage;
H341 Suspected of causing genetic defects;
H360FD May damage fertility. May damage the unborn child;
H372 Causes damage to organs through prolonged or repeated exposure;
H317 Very toxic to aquatic life with long-lasting effects;
H410 Very toxic to aquatic life with long-lasting effects]
to
[H330 Fatal if inhaled;
H301 Toxic if swallowed;
H312 Harmful in contact with skin;
H314 Causes severe skin burns and eye damage;
H341 Suspected of causing genetic defects;
H360FD May damage fertility. May damage the unborn child;
H372 Causes damage to organs through prolonged or repeated exposure if swallowed;
H317 Very toxic to aquatic life with long-lasting effects;
H410 Very toxic to aquatic life with long-lasting effects]
Sources modified from
[N,EU]
to
[EU,A]
08/04/2022 CutOffs modified from
[Skin corrosion - category 1B (H314): concentration >= 5%;
Skin irritation - category 2 (H315): concentration: 0.01% <= concentration < 5%;
Eye damage - category 1 (H318): 3% <= concentration < 5%;
Eye Irritation - category 2 (H319): 0.01% <= concentration <3%;

M = 10 (acute)]
to
[

Skin corrosion - category 1B (H314): concentration >= 5%;
Skin irritation - category 2 (H315): 0.01% <= concentration < 5%;
Eye damage - category 1 (H318): 3% <= concentration < 5%;
Eye Irritation - category 2 (H319): 0.01% <= concentration <3%;

M = 10 (acute)

]
Hazard Category modified from
[HC065:Acute toxicity (inhalation) - category 2,
HC071:Acute toxicity (ingestion) - category 3,
HC077:Acute toxicity (dermal) - category 4,
HC081:Skin corrosion – category 1B,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

to
[HC065:Acute toxicity (inhalation) - category 2,
HC071:Acute toxicity (ingestion) - category 3,
HC077:Acute toxicity (dermal) - category 4,
HC081:Skin corrosion – category 1B,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]
08/04/2022 CutOffs modified from
[]
to
[Skin corrosion - category 1B (H314): concentration >= 5%;
Skin irritation - category 2 (H315): concentration: 0.01% <= concentration < 5%;
Eye damage - category 1 (H318): 3% <= concentration < 5%;
Eye Irritation - category 2 (H319): 0.01% <= concentration <3%;

M = 10 (acute)]
Synonym modified from
[(DBTC);
Stannane, dibutyldichloro-]
to
[ DBTC;
Stannane, dibutyldichloro-]
Hazard Category modified from
[HC060:Acute toxicity – category 2,
HC061:Acute toxicity – category 3,
HC062:Acute toxicity – category 4,
HC081:Skin corrosion – category 1B,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

to
[HC065:Acute toxicity (inhalation) - category 2,
HC071:Acute toxicity (ingestion) - category 3,
HC077:Acute toxicity (dermal) - category 4,
HC081:Skin corrosion – category 1B,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

Hazard Statement modified from
[H330 Fatal if inhaled;
H301 Toxic if swallowed;
H312 Harmful in contact with skin;
H314 Causes severe skin burns and eye damage;
H341 Suspected of causing genetic defects;
H360FD May damage fertility. May damage the unborn child;
H372 Causes damage to organs through prolonged or repeated exposure;
H410 Very toxic to aquatic life with long-lasting effects]
to
[H330 Fatal if inhaled;
H301 Toxic if swallowed;
H312 Harmful in contact with skin;
H314 Causes severe skin burns and eye damage;
H341 Suspected of causing genetic defects;
H360FD May damage fertility. May damage the unborn child;
H372 Causes damage to organs through prolonged or repeated exposure;
H317 Very toxic to aquatic life with long-lasting effects;
H410 Very toxic to aquatic life with long-lasting effects]
Notes modified from
[8 ]
to
[8 , 17 ]
09/05/2018 Synonym modified from
[ (DBTC)]
to
[(DBTC);
Stannane, dibutyldichloro-]
Hazard Category modified from
[HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC060:Acute toxicity – category 2,
HC061:Acute toxicity – category 3,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC081:Skin corrosion – category 1B,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC062:Acute toxicity – category 4,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

to
[HC060:Acute toxicity – category 2,
HC061:Acute toxicity – category 3,
HC062:Acute toxicity – category 4,
HC081:Skin corrosion – category 1B,
HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

Pictogram modified from
[GHS06,GHS05,GHS08,GHS09]
to
[GHS05,GHS06,GHS08,GHS09]
Hazard Statement modified from
[H341 Suspected of causing genetic defects;
H360FD May damage fertility. May damage the unborn child;
H330 Fatal if inhaled;
H301 Toxic if swallowed;
H312 Harmful in contact with skin;
H372 Causes damage to organs through prolonged or repeated exposure;
H314 Causes severe skin burns and eye damage;
H410 Very toxic to aquatic life with long-lasting effects]
to
[H330 ;
H301 ;
H312 ;
H314 ;
H341 ;
H360FD ;
H372 ;
H410 ]
Sources modified from
[EU]
to
[N,EU]
25/11/2016 Hazard Category modified from
[HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC060:Acute toxicity – category 2,
HC061:Acute toxicity – category 3,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC081:Skin corrosion – category 1B,
HC115:Hazardous to the aquatic environment (acute) – category 1]

to
[HC098:Germ cell mutagenicity – category 2,
HC105:Reproductive toxicity – category 1B,
HC060:Acute toxicity – category 2,
HC061:Acute toxicity – category 3,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC081:Skin corrosion – category 1B,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC062:Acute toxicity – category 4,
HC118:Hazardous to the aquatic environment (chronic) – category 1]
23/06/2016 Chemical Added



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