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| Cas Number | 25376-45-8 |
| Chemical Name | 1,3-Benzenediamine, aromatic methyl- |
| Chemical Synonym |
Diaminotoluene tolylenediamine TDA m-TDA methylphenylenediamine |
| Hazard Category |
Carcinogenicity – category 1B Germ cell mutagenicity – category 2 Specific target organ toxicity (repeated exposure) – category 2 Reproductive toxicity – category 2 Skin sensitisation – category 1 Acute toxicity (ingestion) - category 3 Acute toxicity (dermal) - category 4 |
| Hazard Statement |
H350 (May cause cancer) H341 (Suspected of causing genetic defects) H373 (May cause damage to organs through prolonged or repeated exposure through the oral route) H317 (May cause an allergic skin reaction) H361f (Suspected of damaging fertility) H301 (Toxic if swallowed) H312 (Harmful in contact with skin) |
| Pictogram |
GHS06 (Skull and Crossbones) 
GHS08 (Health Hazard) |
| Signal Word | Danger |
| Cut-offs | |
| Notes |
8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.) |
| Sources |
A (The classification information for this entry was provided by the Australian Industrial Chemicals Introduction Scheme) |
Hazardous Chemical History
| Date | Description |
|---|---|
| 18/08/2021 |
Synonym modified from [] to [Diaminotoluene; tolylenediamine; TDA ; m-TDA; methylphenylenediamine ] Hazard Category modified from [HC101:Carcinogenicity – category 1B, HC098:Germ cell mutagenicity – category 2, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC106:Reproductive toxicity – category 2, HC092:Skin sensitisation – category 1, HC071:Acute toxicity (ingestion) - category 3, HC077:Acute toxicity (dermal) - category 4] to [HC071:Acute toxicity (ingestion) - category 3, HC077:Acute toxicity (dermal) - category 4, HC092:Skin sensitisation – category 1, HC098:Germ cell mutagenicity – category 2, HC101:Carcinogenicity – category 1B, HC106:Reproductive toxicity – category 2, HC112:Specific target organ toxicity (repeated exposure) – category 2] Hazard Statement modified from [H350 May cause cancer; H341 Suspected of causing genetic defects; H373 May cause damage to organs through prolonged or repeated exposure if swallowed; H317 May cause an allergic skin reaction; H361f Suspected of damaging fertility; H301 Toxic if swallowed; H312 Harmful in contact with skin] to [H350 May cause cancer; H341 Suspected of causing genetic defects; H373 May cause damage to organs through prolonged or repeated exposure through the oral route; H317 May cause an allergic skin reaction; H361f Suspected of damaging fertility; H301 Toxic if swallowed; H312 Harmful in contact with skin] |
| 18/08/2021 |
Hazard Category modified from [HC061:Acute toxicity – category 3, HC062:Acute toxicity – category 4, HC101:Carcinogenicity – category 1B, HC098:Germ cell mutagenicity – category 2, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC106:Reproductive toxicity – category 2, HC092:Skin sensitisation – category 1] to [HC071:Acute toxicity (ingestion) - category 3, HC077:Acute toxicity (dermal) - category 4, HC092:Skin sensitisation – category 1, HC098:Germ cell mutagenicity – category 2, HC101:Carcinogenicity – category 1B, HC106:Reproductive toxicity – category 2, HC112:Specific target organ toxicity (repeated exposure) – category 2] Hazard Statement modified from [H301 Toxic if swallowed; H312 Harmful in contact with skin; H350 May cause cancer; H341 Suspected of causing genetic defects; H373 May cause damage to organs through prolonged or repeated exposure if swallowed; H317 May cause an allergic skin reaction; H361f Suspected of damaging fertility] to [H350 May cause cancer; H341 Suspected of causing genetic defects; H373 May cause damage to organs through prolonged or repeated exposure if swallowed; H317 May cause an allergic skin reaction; H361f Suspected of damaging fertility; H301 Toxic if swallowed; H312 Harmful in contact with skin] Sources modified from [N] to [A] |
| 09/03/2021 |
Hazard Category modified from [HC061:Acute toxicity – category 3, HC062:Acute toxicity – category 4, HC101:Carcinogenicity – category 1B, HC098:Germ cell mutagenicity – category 2, HC112:Specific target organ toxicity (repeated exposure) – category 2, HC106:Reproductive toxicity – category 2, HC092:Skin sensitisation – category 1] to [HC061:Acute toxicity – category 3, HC062:Acute toxicity – category 4, HC092:Skin sensitisation – category 1, HC098:Germ cell mutagenicity – category 2, HC101:Carcinogenicity – category 1B, HC106:Reproductive toxicity – category 2, HC112:Specific target organ toxicity (repeated exposure) – category 2] Hazard Statement modified from [H301 Toxic if swallowed; H312 Harmful in contact with skin; H350 May cause cancer; H341 Suspected of causing genetic defects; H373 May cause damage to organs through prolonged or repeated exposure if swallowed; H361 Suspected of damaging fertility or the unborn child; H317 May cause an allergic skin reaction] to [H301 Toxic if swallowed; H312 Harmful in contact with skin; H350 May cause cancer; H341 Suspected of causing genetic defects; H373 May cause damage to organs through prolonged or repeated exposure if swallowed; H317 May cause an allergic skin reaction; H361f Suspected of damaging fertility] |
| 09/05/2018 |
Signal Word modified from [] to [Danger] Pictogram modified from [] to [GHS06,GHS08] Hazard Statement modified from [H301 Toxic if swallowed; H312 Harmful in contact with skin; H350 May cause cancer; H341 Suspected of causing genetic defects; H373 May cause damage to organs through prolonged or repeated exposure if swallowed; H361 Suspected of damaging fertility or the unborn child; H317 May cause an allergic skin reaction] to [H301 ; H312 ; H350 ; H341 ; H373 May cause damage to organs through prolonged or repeated exposure if swallowed; H361 ; H317 ] Notes modified from [] to [8] Sources modified from [] to [N] |
| 20/01/2017 | Chemical Deleted |
| 20/01/2017 | Chemical Added |