Hazardous Chemical Information System (HCIS)



Hazardous Chemical Details

Cas Number 26471-62-5
Chemical Name m-tolylidene diisocyanate
Chemical Synonym toluene-diisocyanate
Benzene, 1,3-diisocyanatomethyl-
Hazard Category Carcinogenicity – category 2
Acute toxicity – category 1
Eye irritation – category 2A
Specific target organ toxicity (single exposure) – category 3
Respiratory sensitisation – category 1
Skin sensitisation – category 1
Hazardous to the aquatic environment (chronic) – category 3
Skin irritation – category 2
Hazard Statement H351 (Suspected of causing cancer)
H330 (Fatal if inhaled)
H319 (Causes serious eye irritation)
H335 (May cause respiratory irritation)
H315 (Causes skin irritation)
H334 (May cause allergy or asthma symptoms or breathing difficulties if inhaled)
H317 (May cause an allergic skin reaction)
H412 (Harmful to aquatic life with long-lasting effects)
Pictogram Pictogram of Skull and Crossbones GHS06 (Skull and Crossbones)
Pictogram of Health Hazard GHS08 (Health Hazard)
Signal Word Danger
Cut-offs
Notes C (Some organic substances may be marketed either in a specific isomeric form or as a mixture of several isomers.In this case the supplier should state on the label whether the substance is a specific isomer or a mixture of isomers.)
8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.)
Sources N (The classification information for this entry was provided by the National Industrial Chemical Notification and Assessment Scheme)
EU (Classification information for chemical is taken from the European Union’s Classification, Labelling and Packaging (CLP) Regulation.)

Hazardous Chemical History

Date Description
25/11/2016 Hazard Category modified from
[HC102:Carcinogenicity – category 2,
HC059:Acute toxicity – category 1,
HC087:Eye irritation – category 2A,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC089:Respiratory sensitisation – category 1,
HC092:Skin sensitisation – category 1,
HC120:Hazardous to the aquatic environment (chronic) – category 3]

to
[HC102:Carcinogenicity – category 2,
HC059:Acute toxicity – category 1,
HC087:Eye irritation – category 2A,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC089:Respiratory sensitisation – category 1,
HC092:Skin sensitisation – category 1,
HC120:Hazardous to the aquatic environment (chronic) – category 3,
HC083:Skin irritation – category 2]
23/06/2016 Chemical Added