Hazardous Chemical Information System (HCIS)



Hazardous Chemical Details

Cas Number 137-26-8
Chemical Name thiram (ISO)
Chemical Synonym tetramethylthiuram disulphide
Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), tetramethyl-
tetramethylthiuram disulfide
Hazard Category Acute toxicity – category 4
Acute toxicity – category 4
Skin irritation – category 2
Eye irritation – category 2A
Skin sensitisation – category 1
Germ cell mutagenicity – category 2
Specific target organ toxicity (repeated exposure) – category 2
Hazardous to the aquatic environment (acute) – category 1
Hazardous to the aquatic environment (chronic) – category 1
Hazard Statement H302 (Harmful if swallowed)
H332 (Harmful if inhaled)
H315 (Causes skin irritation)
H319 (Causes serious eye irritation)
H317 (May cause an allergic skin reaction)
H341 (Suspected of causing genetic defects)
H373 (May cause damage to organs through prolonged or repeated exposure through the oral route)
H410 (Very toxic to aquatic life with long-lasting effects)
Pictogram Pictogram of Exclamation Mark GHS07 (Exclamation Mark)
Pictogram of Health Hazard GHS08 (Health Hazard)
Pictogram of Environment GHS09 (Environment)
Signal Word Warning
Cut-offs

M = 10 (acute)

Notes 8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.)
Sources N (The classification information for this entry was provided by the National Industrial Chemical Notification and Assessment Scheme)
EU (Classification information for chemical is taken from the European Union’s Classification, Labelling and Packaging (CLP) Regulation.)

Hazardous Chemical History

Date Description
30/04/2021 CutOffs modified from
[M = 10 (acute)]
to
[

M = 10 (acute)

]
Hazard Statement modified from
[H302 Harmful if swallowed;
H332 Harmful if inhaled;
H315 Causes skin irritation;
H319 Causes serious eye irritation;
H317 May cause an allergic skin reaction;
H341 Suspected of causing genetic defects;
H373 May cause damage to organs through prolonged or repeated exposure;
H410 Very toxic to aquatic life with long-lasting effects]
to
[H302 Harmful if swallowed;
H332 Harmful if inhaled;
H315 Causes skin irritation;
H319 Causes serious eye irritation;
H317 May cause an allergic skin reaction;
H341 Suspected of causing genetic defects;
H373 May cause damage to organs through prolonged or repeated exposure through the oral route;
H410 Very toxic to aquatic life with long-lasting effects]
30/04/2021 CutOffs modified from
[]
to
[M = 10 (acute)]
Synonym modified from
[ tetramethylthiuram disulphide;
Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), tetramethyl-;
tetramethylthiuram disulfide]
to
[tetramethylthiuram disulphide;
Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), tetramethyl-;
tetramethylthiuram disulfide]
26/07/2019 Synonym modified from
[ tetramethylthiuram disulphide;
Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), tetramethyl-]
to
[ tetramethylthiuram disulphide;
Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), tetramethyl-;
tetramethylthiuram disulfide]
09/05/2018 Synonym modified from
[ tetramethylthiuram disulphide]
to
[ tetramethylthiuram disulphide;
Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), tetramethyl-]
Hazard Category modified from
[HC062:Acute toxicity – category 4,
HC062:Acute toxicity – category 4,
HC112:Specific target organ toxicity (repeated exposure) – category 2,
HC086:Eye irritation – category 2,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1,
HC083:Skin irritation – category 2]

to
[HC062:Acute toxicity – category 4,
HC062:Acute toxicity – category 4,
HC083:Skin irritation – category 2,
HC087:Eye irritation – category 2A,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC112:Specific target organ toxicity (repeated exposure) – category 2,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

Pictogram modified from
[GHS08,GHS07,GHS09]
to
[GHS07,GHS08,GHS09]
Hazard Statement modified from
[H332 Harmful if inhaled;
H302 Harmful if swallowed;
H373 May cause damage to organs through prolonged or repeated exposure;
H319 Causes serious eye irritation;
H315 Causes skin irritation;
H317 May cause an allergic skin reaction;
H410 Very toxic to aquatic life with long-lasting effects]
to
[H302 ;
H332 ;
H315 ;
H319 ;
H317 ;
H341 ;
H373 ;
H410 ]
Sources modified from
[EU]
to
[N,EU]
25/11/2016 Hazard Category modified from
[HC062:Acute toxicity – category 4,
HC062:Acute toxicity – category 4,
HC112:Specific target organ toxicity (repeated exposure) – category 2,
HC086:Eye irritation – category 2,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

to
[HC062:Acute toxicity – category 4,
HC062:Acute toxicity – category 4,
HC112:Specific target organ toxicity (repeated exposure) – category 2,
HC086:Eye irritation – category 2,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1,
HC083:Skin irritation – category 2]
23/06/2016 Chemical Added