Hazardous Chemical Information System (HCIS)



Hazardous Chemical Details

Cas Number 106-51-4
Chemical Name p-benzoquinone
Chemical Synonym quinone
1,4-quinone
1,4-benzoquine
1,4-cyclohexadiene dioxide
cyclohexa-2,5-diene-1,4-dione
2,5-Cyclohexadiene-1,4-dione
Hazard Category Acute toxicity (ingestion) - category 3
Acute toxicity (inhalation) - category 3
Skin irritation – category 2
Eye irritation – category 2A
Skin sensitisation – category 1B
Specific target organ toxicity (single exposure) – category 3
Germ cell mutagenicity – category 2
Hazard Statement H301 (Toxic if swallowed)
H331 (Toxic if inhaled)
H315 (Causes skin irritation)
H319 (Causes serious eye irritation)
H317 (May cause an allergic skin reaction)
H335 (May cause respiratory irritation)
H341 (Suspected of causing genetic defects)
Pictogram Pictogram of Skull and Crossbones GHS06 (Skull and Crossbones)
Pictogram of Health Hazard GHS08 (Health Hazard)
Signal Word Danger
Cut-offs
Notes 8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.)
Sources A (The classification information for this entry was provided by the Australian Industrial Chemicals Introduction Scheme)

Hazardous Chemical History

Date Description
09/08/2023 Pictogram modified from
[GHS06,GHS08,GHS09]
to
[GHS06,GHS08]
Hazard Statement modified from
[H301 Toxic if swallowed;
H331 Toxic if inhaled;
H315 Causes skin irritation;
H319 Causes serious eye irritation;
H317 May cause an allergic skin reaction;
H335 May cause respiratory irritation;
H341 Suspected of causing genetic defects;
H400 Very toxic to aquatic life]
to
[H301 Toxic if swallowed;
H331 Toxic if inhaled;
H315 Causes skin irritation;
H319 Causes serious eye irritation;
H317 May cause an allergic skin reaction;
H335 May cause respiratory irritation;
H341 Suspected of causing genetic defects]
09/08/2023 Hazard Category modified from
[HC071:Acute toxicity (ingestion) - category 3,
HC066:Acute toxicity (inhalation) - category 3,
HC083:Skin irritation – category 2,
HC087:Eye irritation – category 2A,
HC094:Skin sensitisation – category 1B,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC098:Germ cell mutagenicity – category 2,
HC115:Hazardous to the aquatic environment (acute) – category 1]

to
[HC071:Acute toxicity (ingestion) - category 3,
HC066:Acute toxicity (inhalation) - category 3,
HC083:Skin irritation – category 2,
HC087:Eye irritation – category 2A,
HC094:Skin sensitisation – category 1B,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC098:Germ cell mutagenicity – category 2]
09/08/2023 Pictogram modified from
[GHS06,GHS08]
to
[GHS06,GHS08,GHS09]
Sources modified from
[A,EU]
to
[A]
09/08/2023 CutOffs modified from
[

M = 10 (acute)

]
to
[]
Synonym modified from
[ quinone]
to
[quinone;
1,4-quinone;
1,4-benzoquine;
1,4-cyclohexadiene dioxide;
cyclohexa-2,5-diene-1,4-dione;
2,5-Cyclohexadiene-1,4-dione]
Hazard Category modified from
[HC061:Acute toxicity – category 3,
HC061:Acute toxicity – category 3,
HC086:Eye irritation – category 2,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC083:Skin irritation – category 2]

to
[HC071:Acute toxicity (ingestion) - category 3,
HC066:Acute toxicity (inhalation) - category 3,
HC083:Skin irritation – category 2,
HC087:Eye irritation – category 2A,
HC094:Skin sensitisation – category 1B,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC098:Germ cell mutagenicity – category 2,
HC115:Hazardous to the aquatic environment (acute) – category 1]

Pictogram modified from
[GHS06,GHS09]
to
[GHS06,GHS08]
Hazard Statement modified from
[H331 Toxic if inhaled;
H301 Toxic if swallowed;
H319 Causes serious eye irritation;
H335 May cause respiratory irritation;
H315 Causes skin irritation;
H400 Very toxic to aquatic life]
to
[H301 Toxic if swallowed;
H331 Toxic if inhaled;
H315 Causes skin irritation;
H319 Causes serious eye irritation;
H317 May cause an allergic skin reaction;
H335 May cause respiratory irritation;
H341 Suspected of causing genetic defects;
H400 Very toxic to aquatic life]
Sources modified from
[EU]
to
[A,EU]
09/08/2023 CutOffs modified from
[]
to
[

M = 10 (acute)

]
Hazard Category modified from
[HC061:Acute toxicity – category 3,
HC061:Acute toxicity – category 3,
HC086:Eye irritation – category 2,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC083:Skin irritation – category 2]

to
[HC061:Acute toxicity – category 3,
HC061:Acute toxicity – category 3,
HC083:Skin irritation – category 2,
HC086:Eye irritation – category 2,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC115:Hazardous to the aquatic environment (acute) – category 1]
25/11/2016 Hazard Category modified from
[HC061:Acute toxicity – category 3,
HC061:Acute toxicity – category 3,
HC086:Eye irritation – category 2,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC115:Hazardous to the aquatic environment (acute) – category 1]

to
[HC061:Acute toxicity – category 3,
HC061:Acute toxicity – category 3,
HC086:Eye irritation – category 2,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC083:Skin irritation – category 2]
23/06/2016 Chemical Added