Hazardous Chemical Information System (HCIS)



Hazardous Chemical Details

Cas Number 95-54-5
Chemical Name 1,2-Benzenediamine
Chemical Synonym o-phenylenediamine
Hazard Category Carcinogenicity – category 2
Germ cell mutagenicity – category 2
Eye irritation – category 2A
Skin sensitisation – category 1
Hazardous to the aquatic environment (acute) – category 1
Hazardous to the aquatic environment (chronic) – category 1
Acute toxicity (ingestion) - category 3
Acute toxicity (inhalation) - category 4
Acute toxicity (dermal) - category 4
Hazard Statement H351 (Suspected of causing cancer)
H341 (Suspected of causing genetic defects)
H312 (Harmful in contact with skin)
H319 (Causes serious eye irritation)
H317 (May cause an allergic skin reaction)
H410 (Very toxic to aquatic life with long-lasting effects)
H301 (Toxic if swallowed)
H332 (Harmful if inhaled)
Pictogram Pictogram of Skull and Crossbones GHS06 (Skull and Crossbones)
Pictogram of Health Hazard GHS08 (Health Hazard)
Pictogram of Environment GHS09 (Environment)
Signal Word Danger
Cut-offs
Notes 8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.)
Sources EU (Classification information for chemical is taken from the European Union’s Classification, Labelling and Packaging (CLP) Regulation.)
A (The classification information for this entry was provided by the Australian Industrial Chemicals Introduction Scheme)

Hazardous Chemical History

Date Description
18/08/2021 Hazard Category modified from
[HC102:Carcinogenicity – category 2,
HC098:Germ cell mutagenicity – category 2,
HC087:Eye irritation – category 2A,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1,
HC071:Acute toxicity (ingestion) - category 3,
HC067:Acute toxicity (inhalation) - category 4]

to
[HC067:Acute toxicity (inhalation) - category 4,
HC071:Acute toxicity (ingestion) - category 3,
HC077:Acute toxicity (dermal) - category 4,
HC087:Eye irritation – category 2A,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC102:Carcinogenicity – category 2,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]
18/08/2021 Hazard Category modified from
[HC102:Carcinogenicity – category 2,
HC098:Germ cell mutagenicity – category 2,
HC061:Acute toxicity – category 3,
HC062:Acute toxicity – category 4,
HC087:Eye irritation – category 2A,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

to
[HC067:Acute toxicity (inhalation) - category 4,
HC071:Acute toxicity (ingestion) - category 3,
HC087:Eye irritation – category 2A,
HC092:Skin sensitisation – category 1,
HC098:Germ cell mutagenicity – category 2,
HC102:Carcinogenicity – category 2,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]

Hazard Statement modified from
[H351 Suspected of causing cancer;
H341 Suspected of causing genetic defects;
H301 Toxic if swallowed;
H332 Harmful if inhaled;
H312 Harmful in contact with skin;
H319 Causes serious eye irritation;
H317 May cause an allergic skin reaction;
H410 Very toxic to aquatic life with long-lasting effects]
to
[H351 Suspected of causing cancer;
H341 Suspected of causing genetic defects;
H312 Harmful in contact with skin;
H319 Causes serious eye irritation;
H317 May cause an allergic skin reaction;
H410 Very toxic to aquatic life with long-lasting effects;
H301 Toxic if swallowed;
H332 Harmful if inhaled]
Sources modified from
[N,EU]
to
[EU,A]
25/11/2016 Hazard Category modified from
[HC102:Carcinogenicity – category 2,
HC098:Germ cell mutagenicity – category 2,
HC061:Acute toxicity – category 3,
HC062:Acute toxicity – category 4,
HC087:Eye irritation – category 2A,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1]

to
[HC102:Carcinogenicity – category 2,
HC098:Germ cell mutagenicity – category 2,
HC061:Acute toxicity – category 3,
HC062:Acute toxicity – category 4,
HC087:Eye irritation – category 2A,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC118:Hazardous to the aquatic environment (chronic) – category 1]
23/06/2016 Chemical Added