Hazardous Chemical Information System (HCIS)



Hazardous Chemical Details

Cas Number 7601-90-3
Chemical Name perchloric acid ... %
Chemical Synonym
Hazard Category Oxidising liquid – category 1
Acute toxicity – category 4
Skin corrosion – category 1A
Hazard Statement H271 (May cause fire or explosion; strong oxidiser)
H302 (Harmful if swallowed)
H314 (Causes severe skin burns and eye damage)
Pictogram Pictogram of Flame Over Circle GHS03 (Flame Over Circle)
Pictogram of Exclamation Mark GHS07 (Exclamation Mark)
Pictogram of Corrosion GHS05 (Corrosion)
Signal Word Danger
Cut-offs

Skin corrosion - category 1A (H314): concentration >= 50%;
Skin corrosion - category 1B (H314): 10% <= concentration < 50%;
Skin irritation - category 2 (H315): 1% <=  concentration < 10%;
Eye irritation - category 2 (H319): 1% <= concentration < 10%;
Oxidising liquid - category 1 (H271): concentration > 50%;
Oxidising liquid - category 2 (H272): concentration <= 50%

Notes B (Some substances (acids, bases, etc.) are placed on the market in aqueous solutions at various concentrations and, therefore, these solutions require different classification and labelling since the hazards vary at different concentrations.Entries with Note B have a general designation of the following type: ‘nitric acid … %’.In this case the supplier should state the percentage concentration of the solution on the label. Unless otherwise stated, it is assumed that the percentage concentration is calculated on a weight/weight basis.)
17 (Generic cut off concentrations also apply to this chemical in addition to the specific cut off concentration(s) above. Refer to the generic cut off concentration table on the Reference Information page of HCIS (http://hcis.safeworkaustralia.gov.au/UserGuide).)
Sources N (The classification information for this entry was provided by the National Industrial Chemical Notification and Assessment Scheme)
EU (Classification information for chemical is taken from the European Union’s Classification, Labelling and Packaging (CLP) Regulation.)

Hazardous Chemical History

Date Description
30/04/2021 Pictogram modified from
[GHS03,GHS07,GHS05]
to
[GHS03,GHS05,GHS07]
Hazard Statement modified from
[H271 May cause fire or explosion; strong oxidiser;
H314 Harmful if swallowed;
H302 Harmful if swallowed]
to
[H271 May cause fire or explosion; strong oxidiser;
H302 Harmful if swallowed;
H314 Causes severe skin burns and eye damage]
30/04/2021 Pictogram modified from
[GHS03,GHS07,GHS05]
to
[GHS03,GHS05,GHS07]
Hazard Statement modified from
[H271 May cause fire or explosion;
H314 Harmful if swallowed;
H302 Harmful if swallowed]
to
[H271 May cause fire or explosion; strong oxidiser;
H314 Harmful if swallowed;
H302 Harmful if swallowed]
30/04/2021 CutOffs modified from
[Skin corrosion - category 1A (H314): concentration >= 50%;
Skin corrosion - category 1B (H314): 10% <= concentration < 50%;
Skin irritation - category 2 (H315): 1% <=  concentration < 10%;
Eye irritation - category 2 (H319): 1% <= concentration < 10%;
Oxidising liquid - category 1 (H271): concentration > 50%;
Oxidising liquid - category 2 (H272): concentration <= 50%]
to
[

Skin corrosion - category 1A (H314): concentration >= 50%;
Skin corrosion - category 1B (H314): 10% <= concentration < 50%;
Skin irritation - category 2 (H315): 1% <=  concentration < 10%;
Eye irritation - category 2 (H319): 1% <= concentration < 10%;
Oxidising liquid - category 1 (H271): concentration > 50%;
Oxidising liquid - category 2 (H272): concentration <= 50%

]
Pictogram modified from
[GHS03,GHS07,GHS05]
to
[GHS03,GHS05,GHS07]
Hazard Statement modified from
[H271 May cause fire or explosion;
H302 strong oxidizer;
H314 Harmful if swallowed]
to
[H271 May cause fire or explosion;
H314 Harmful if swallowed;
H302 Harmful if swallowed]
30/04/2021 CutOffs modified from
[]
to
[Skin corrosion - category 1A (H314): concentration >= 50%;
Skin corrosion - category 1B (H314): 10% <= concentration < 50%;
Skin irritation - category 2 (H315): 1% <=  concentration < 10%;
Eye irritation - category 2 (H319): 1% <= concentration < 10%;
Oxidising liquid - category 1 (H271): concentration > 50%;
Oxidising liquid - category 2 (H272): concentration <= 50%]
Pictogram modified from
[GHS03,GHS07,GHS05]
to
[GHS03,GHS05,GHS07]
Hazard Statement modified from
[H271 May cause fire or explosion; strong oxidizer;
H302 Harmful if swallowed;
H314 Causes severe skin burns and eye damage]
to
[H271 May cause fire or explosion;
H302 strong oxidizer;
H314 Harmful if swallowed]
Notes modified from
[B ]
to
[B , 17 ]
09/05/2018 Signal Word modified from
[]
to
[Danger]
Hazard Category modified from
[HC062:Acute toxicity – category 4,
HC080:Skin corrosion – category 1A]

to
[HC041:Oxidising liquid – category 1,
HC062:Acute toxicity – category 4,
HC080:Skin corrosion – category 1A]

Pictogram modified from
[]
to
[GHS03,GHS07,GHS05]
Hazard Statement modified from
[H302 Harmful if swallowed;
H314 Causes severe skin burns and eye damage]
to
[H271 ;
H302 ;
H314 ]
Notes modified from
[]
to
[B]
Sources modified from
[]
to
[N,EU]
20/01/2017 Chemical Deleted
20/01/2017 Signal Word modified from
[Danger]
to
[]
Hazard Category modified from
[HC041:Oxidising liquid – category 1,
HC080:Skin corrosion – category 1A]

to
[HC062:Acute toxicity – category 4,
HC080:Skin corrosion – category 1A]

Pictogram modified from
[GHS03,GHS05]
to
[]
Hazard Statement modified from
[H271 May cause fire or explosion; strong oxidizer;
H314 Causes severe skin burns and eye damage]
to
[H302 ;
H314 ]
Notes modified from
[B]
to
[]
Sources modified from
[EU]
to
[]
23/06/2016 Chemical Added