Hazardous Chemical Information System (HCIS)



Hazardous Chemical Details

Cas Number 7803-49-8
Chemical Name hydroxylamine ....% [> 55 % in aqueous solution]
Chemical Synonym
Hazard Category Corrosive to metals – category 1
Acute toxicity – category 4
Acute toxicity – category 4
Carcinogenicity – category 2
Skin irritation – category 2
Specific target organ toxicity (repeated exposure) – category 1
Skin sensitisation – category 1
Eye damage – category 1
Hazardous to the aquatic environment (acute) – category 1
Specific target organ toxicity (single exposure) – category 3
Hazard Statement H290 (May be corrosive to metals)
H302 (Harmful if swallowed)
H312 (Harmful in contact with skin)
H351 (Suspected of causing cancer)
H315 (Causes skin irritation)
H372 (Causes damage to organs through prolonged or repeated exposure)
H317 (May cause an allergic skin reaction)
H318 (Causes serious eye damage)
H400 (Very toxic to aquatic life)
H335 (May cause respiratory irritation)
Pictogram Pictogram of Corrosion GHS05 (Corrosion)
Pictogram of Exclamation Mark GHS07 (Exclamation Mark)
Pictogram of Health Hazard GHS08 (Health Hazard)
Pictogram of Environment GHS09 (Environment)
Signal Word Danger
Cut-offs hydroxylamine ....% > 55 % in aqueous solution has hazard category and statement ‘unstable explosive'.
Notes B (Some substances (acids, bases, etc.) are placed on the market in aqueous solutions at various concentrations and, therefore, these solutions require different classification and labelling since the hazards vary at different concentrations.Entries with Note B have a general designation of the following type: ‘nitric acid … %’.In this case the supplier should state the percentage concentration of the solution on the label. Unless otherwise stated, it is assumed that the percentage concentration is calculated on a weight/weight basis.)
8 (The tables in schedule 6 of the WHS regulations replace some tables in the GHS, this may affect the cut off concentrations for this chemical.)
Sources N (The classification information for this entry was provided by the National Industrial Chemical Notification and Assessment Scheme)
EU (Classification information for chemical is taken from the European Union’s Classification, Labelling and Packaging (CLP) Regulation.)

Hazardous Chemical History

Date Description
19/07/2019 Hazard Category modified from
[HC054:Corrosive to metals – category 1,
HC062:Acute toxicity – category 4,
HC062:Acute toxicity – category 4,
HC102:Carcinogenicity – category 2,
HC083:Skin irritation – category 2,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC092:Skin sensitisation – category 1,
HC085:Eye damage – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC087:Eye irritation – category 2A]

to
[HC054:Corrosive to metals – category 1,
HC062:Acute toxicity – category 4,
HC062:Acute toxicity – category 4,
HC102:Carcinogenicity – category 2,
HC083:Skin irritation – category 2,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC092:Skin sensitisation – category 1,
HC085:Eye damage – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC110:Specific target organ toxicity (single exposure) – category 3]

Hazard Statement modified from
[H290 May be corrosive to metals;
H302 Harmful if swallowed;
H312 Harmful in contact with skin;
H351 Suspected of causing cancer;
H315 Causes skin irritation;
H372 Causes damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction;
H318 Causes serious eye damage;
H400 Very toxic to aquatic life;
H319 Causes serious eye irritation]
to
[H290 May be corrosive to metals;
H302 Harmful if swallowed;
H312 Harmful in contact with skin;
H351 Suspected of causing cancer;
H315 Causes skin irritation;
H372 Causes damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction;
H318 Causes serious eye damage;
H400 Very toxic to aquatic life;
H335 May cause respiratory irritation]
25/06/2018 Hazard Category modified from
[HC054:Corrosive to metals – category 1,
HC062:Acute toxicity – category 4,
HC062:Acute toxicity – category 4,
HC102:Carcinogenicity – category 2,
HC083:Skin irritation – category 2,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC092:Skin sensitisation – category 1,
HC085:Eye damage – category 1,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC115:Hazardous to the aquatic environment (acute) – category 1]

to
[HC054:Corrosive to metals – category 1,
HC062:Acute toxicity – category 4,
HC062:Acute toxicity – category 4,
HC102:Carcinogenicity – category 2,
HC083:Skin irritation – category 2,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC092:Skin sensitisation – category 1,
HC085:Eye damage – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC087:Eye irritation – category 2A]

Hazard Statement modified from
[H290 May be corrosive to metals;
H302 Harmful if swallowed;
H312 Harmful in contact with skin;
H351 Suspected of causing cancer;
H315 Causes skin irritation;
H372 Causes damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction;
H318 Causes serious eye damage;
H335 May cause respiratory irritation;
H400 Very toxic to aquatic life]
to
[H290 May be corrosive to metals;
H302 Harmful if swallowed;
H312 Harmful in contact with skin;
H351 Suspected of causing cancer;
H315 Causes skin irritation;
H372 Causes damage to organs through prolonged or repeated exposure;
H317 May cause an allergic skin reaction;
H318 Causes serious eye damage;
H400 Very toxic to aquatic life;
H319 Causes serious eye irritation]
09/05/2018 CutOffs modified from
[]
to
[hydroxylamine ....% > 55 % in aqueous solution has hazard category and statement ‘unstable explosive'.]
Hazard Category modified from
[HC002:Unstable explosive,
HC054:Corrosive to metals – category 1,
HC102:Carcinogenicity – category 2,
HC062:Acute toxicity – category 4,
HC112:Specific target organ toxicity (repeated exposure) – category 2,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC083:Skin irritation – category 2,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC085:Eye damage – category 1]

to
[HC054:Corrosive to metals – category 1,
HC062:Acute toxicity – category 4,
HC062:Acute toxicity – category 4,
HC102:Carcinogenicity – category 2,
HC083:Skin irritation – category 2,
HC111:Specific target organ toxicity (repeated exposure) – category 1,
HC092:Skin sensitisation – category 1,
HC085:Eye damage – category 1,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC115:Hazardous to the aquatic environment (acute) – category 1]

Pictogram modified from
[GHS01,GHS05,GHS08,GHS07,GHS09]
to
[GHS05,GHS07,GHS08,GHS09]
Hazard Statement modified from
[H200 Unstable explosive;
H290 May be corrosive to metals;
H351 Suspected of causing cancer;
H312 Harmful in contact with skin;
H302 Harmful if swallowed;
H373 May cause damage to organs through prolonged or repeated exposure;
H335 May cause respiratory irritation;
H315 Causes skin irritation;
H318 Causes serious eye damage;
H317 May cause an allergic skin reaction;
H400 Very toxic to aquatic life]
to
[H290 ;
H302 ;
H312 ;
H351 ;
H315 ;
H372 ;
H317 ;
H318 ;
H335 ;
H400 ]
Sources modified from
[EU]
to
[N,EU]
25/11/2016 Hazard Category modified from
[HC002:Unstable explosive,
HC054:Corrosive to metals – category 1,
HC102:Carcinogenicity – category 2,
HC062:Acute toxicity – category 4,
HC112:Specific target organ toxicity (repeated exposure) – category 2,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC083:Skin irritation – category 2,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1]

to
[HC002:Unstable explosive,
HC054:Corrosive to metals – category 1,
HC102:Carcinogenicity – category 2,
HC062:Acute toxicity – category 4,
HC112:Specific target organ toxicity (repeated exposure) – category 2,
HC110:Specific target organ toxicity (single exposure) – category 3,
HC083:Skin irritation – category 2,
HC092:Skin sensitisation – category 1,
HC115:Hazardous to the aquatic environment (acute) – category 1,
HC085:Eye damage – category 1]
23/06/2016 Chemical Added